Here are some webform hooks which execute before rendering form. These hooks can manipulate form appearance and elements values.
function webform_webform_submission_prepare_form(WebformSubmissionInterface $webform_submission, $operation, FormStateInterface $form_state) {
}
function custom_form_alter(&$form, FormStateInterface $form_state, $form_id) {
$form["elements"]["full_name"]["#title"]='New Title';
}
function custom_preprocess_webform(&$variables) {
}